'Fluorous biphase catalysis (FBC)', 4 a new catalytic procedure, has been developed by Horváth and Rábai in 1994. Since then, this new protocol has been advanced rapidly and a mass of fluorous catalysts 5 and ligands 6 (especially phosphines) are known. FBC is particularly suited for economical and green chemical processes due to the reusable and recoverable of fluorous catalyst and ligands. However, there are hitherto few reports about the application of fluorous catalyst ...