Redox-photosensitized aminations of 1, 2-benzo-1, 3-cycloalkadienes, arylcyclopropanes, and quadricyclane with ammonia

…, R Kojima, H Tsutsui, D Utsunomiya…

Index: Yasuda, Masahide; Kojima, Ryuji; Tsutsui, Hiroshi; Utsunomiya, Daigo; Ishii, Kazuaki; Jinnouchi, Koutaro; Shiragami, Tsutomu Journal of Organic Chemistry, 2003 , vol. 68, # 20 p. 7618 - 7624

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Citation Number: 22

Abstract

1, 2, 4-Triphenylbenzene and 2, 2'-methylenedioxy-1, 1'-binaphthalene successfully photosensitized the aminations of 1, 2-benzo-1, 3-cycloalkadienes, arylcyclopropanes, and quadricyclane with ammonia and primary amines in the presence of m-or p- dicyanobenzene, which gave the 4-amino-1, 2-benzocycloalkenes, 3-amino-1- arylpropanes, and 7-amino-5-(p-cyanophenyl) bicyclo [2.2. 1] hept-2-ene, respectively. A ...