Synthesis of carbosilane dendritic wedges and their use for the construction of dendritic receptors

R van Heerbeek, PCJ Kamer…

Index: Van Heerbeek, Rieko; Kamer, Paul C. J.; Van Leeuwen, Piet N.M.W.; Reek, Joost N.H. Organic and Biomolecular Chemistry, 2006 , vol. 4, # 2 p. 211 - 223

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Citation Number: 19

Abstract

A divergent route for the synthesis of carbosilane wedges that contain either a bromine or amine as focal point has been developed. These new building blocks enable the construction of various core-functionalized carbosilane dendrimers. As a typical example carbosilane dendrimers up to the third generation containing a N, N′, N ″-1, 3, 5- benzenetricarboxamide core (G1–G3) have been synthesized. This new class of ...