Applied Organometallic Chemistry

Highly efficient catalytic system for electrophilic amination of arylzinc reagents

T Daşkapan, S Koca

Index: Daskapan, Tahir; Koca, Selcuk Applied Organometallic Chemistry, 2010 , vol. 24, # 1 p. 12 - 16

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Citation Number: 4

Abstract

Abstract The effect of catalyst on the yield of amine in the amination of three classes of arylzinc reagents with acetone oxime O-tosylate was investigated. Since they allowed the preparation of arylamines in excellent yields in the presence of a minimum amount of copper (I) or copper (II) compounds, the catalytic systems using copper (I) or copper (II) combined with a P-, N-or S-donor ligand were revealed to be the best catalysts for the electrophilic ...