The Axial Effect in the Rearrangement with Nitrous Acid of cis-and trans-2-Amino-1-phenylcyclohexanol1

DY Curtin, S Schmukler

Index: Curtin; Schmukler Journal of the American Chemical Society, 1955 , vol. 77, p. 1105,1108

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Citation Number: 27

Abstract

Bonner, Zderic and Casalette12 have shown that optically active a-hydroxy-a- phenylpropionic acid is converted to optically active a-phenylpropionic acid with retention of configuration. If the removal of the hydroxyl groups of the amino alcohols, cis-and trans-I1 follows a similar steric course, the configurations of cis-and trans-V as indicated above and the configurational assignment previously madelo to trans-V is confirmed. 13 At the same ...