Phosphorus and Sulfur and the Related Elements

ORGANISCHE PHOSPHORVERBINDUNGEN 75: Herstellung und Eigenschaften von Aminomethylendiphosphinaten und-diphosphonaten, RR1NCH [P (O) R2 (OR3 …

L Maier

Index: Maier, Ludwig Phosphorus and Sulfur and the Related Elements, 1981 , vol. 11, p. 311 - 322

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Citation Number: 10

Abstract

Abstract Substituted aminomethylene-bis (phosphinates) are obtained in good yield by the interaction of substituted aminomethylenedichlorides with phosphonites or from the three component reaction consisting of a primary amine, orthoformates and the half-esters of phosphonous acids. 3-Methylpyridyl-2-amino-methylene-bis (O-ethyl-methylphosphinate) hydrolizes easily in water to give the corresponding acid in which neither of the nitrogen ...