Combined ruthenium (II) and lipase catalysis for efficient dynamic kinetic resolution of secondary alcohols. Insight into the racemization mechanism

B Martín-Matute, M Edin, K Bogár…

Index: Journal of the American Chemical Society, , vol. 127, # 24 p. 8817 - 8825

Full Text: HTML

Citation Number: 262

Abstract

... Journal of the ... 2005, 127 (24), pp 8817–8825. DOI: 10.1021/ja051576x. Publication Date (Web): May 27, 2005. Copyright © 2005 American Chemical Society. ... This leads to the presence of ruthenium iodide complex 3c and t-BuOK, and the latter can catalyze chemical acylation of ...