Polynuclear branched tetrazole systems. 3. Acidity of α, ω-ditetrazol-5-ylalkanes

…, RE Trifonov, VV Poborchii, VA Ostrovskii

Index: Zubarev; Trifonov; Poborchii; Ostrovskii Chemistry of Heterocyclic Compounds, 2006 , vol. 42, # 4 p. 469 - 474

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Citation Number: 6

Abstract

Abstract α, ω-Ditetrazol-5-ylalkanes with 1 to 5 methylene groups in the alkyl fragment display the properties of dibasic heterocyclic NH acids with pK a values lying in the range 3.4–6.1. The pK a values of these compounds are in a linear dependence on the values of the dielectric permeability of the medium, on the chemical shifts of the signals of the endocyclic carbon atom, and of the carbon atom of the α-methylene group in the 13 C ...