(6 S)-3-Methylene-6-methyl-1, 4-dioxane-2, 5-dione was synthesized from l-lactide and used as the dienophile to prepare spiro [6-methyl-1, 4-dioxane-2, 5-dione-3, 2′-bicyclo [2.2. 1] hept [5] ene] via an exoselective and diastereofacial-selective Diels− Alder reaction. Polymerizations of this bifunctional lactide derivative were successfully carried out under ring-opening and ring-opening metathesis polymerization conditions to yield high ...
[Leemhuis, Mark; Van Steenis, Jan Hein; Van Uxem, Michelle J.; Van Nostrum, Cornelus F.; Hennink, Wim E. European Journal of Organic Chemistry, 2003 , # 17 p. 3344 - 3349]
[Leemhuis, Mark; Van Steenis, Jan Hein; Van Uxem, Michelle J.; Van Nostrum, Cornelus F.; Hennink, Wim E. European Journal of Organic Chemistry, 2003 , # 17 p. 3344 - 3349]
