The Journal of Organic Chemistry

Steric limits in the reactions of amines with in situ generted. alpha.-lactams. The synthesis of extremely sterically hindered tertiary amines

FS Guziec Jr, FF Torres

Index: Guziec, Frank S.; Torres, Felix F. Journal of Organic Chemistry, 1993 , vol. 58, # 6 p. 1604 - 1606

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Citation Number: 13

Abstract

Sterically hindered amines are very important in a variety of applications. They are particularly useful as proton scavengers in~ ynthesis. l-~ Their metal salts have been invaluable reagents in selective alkylation reactions of carbonyl compounds. 6-ll Industrially, sterically hindered amines are precursors to persistent nitroxyl radicals, important as polymer photo~ tabilizers.~~-~ 5 Hindered amines are also important agents for removal ...