Synthesis

Synthesis of low generation phenylenealkylene dendrons as nonpolar building blocks for a dendrimer construction set

M Beinhoff, B Karakaya, AD Schlüter

Index: Beinhoff, Matthias; Karakaya, Birol; Schlueter, A. Dieter Synthesis, 2003 , # 1 p. 79 - 90

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Citation Number: 11

Abstract

Abstract The gram scale syntheses of first and second generation (G1 and G2) dendrons 1- 4, and 35, based on aryl and alkyl moieties, by Suzuki-Miyaura cross-coupling are presented. Both a divergent and an accelerated convergent route are applied. In addition, first results on the synthesis of hyperbranched oligomers of AB 2 monomer 19 are reported.