Polyhedron

Microwave induced novel synthetic route to organomercurials

M Kidwai, Y Goel

Index: Kidwai, Mazaahir; Goel, Yogesh Polyhedron, 1996 , vol. 15, # 17 p. 2819 - 2824

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Citation Number: 16

Abstract

Organomercurials of 2-mercapto-5-methyl-1, 3, 4-thiadiazole and 2-mercapto-5-[4′-methyl quinolinyl-2-oxy methyl]-1, 3, 4-oxadiazole with aryl mercuric chloride have been synthesized under microwave irradiation in open vessels in a domestic microwave oven within a few minutes. This reaction rate was ca 100 times faster than the reaction rate in the conventional way. These organomercurials have a 1: 1 stoichiometric ratio of aryl mercury ...