Reaction of methylmagnesium iodide with dibutylcyanamide and dibutylnitrosamine

…, RA Karakhanov, VI Kelarev, TS Sheveleva…

Index: Polivin, Yu. N.; Karakhanov, R. A.; Kelarev, V. I.; Sheveleva, T. S.; Ugrak, B. I. Russian Chemical Bulletin, 1993 , vol. 42, # 12 p. 1991 - 1994 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 12 p. 2078 - 2081

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Abstract

Abstract The reaction of methylmagnesium iodide with di (n-butyl) cyanamide results in dibutylamine, dibutylisopropylamine, and acetonitrile, while the reaction with di (n-butyl) nitrosamine affords acetaldehyde dibutylhydrazone. Formaldehyde, acetone, and 2- butanone dibutylhydrazones, as well as acetaldehyde butyl (1-methylbutyl) hydrazone, 2- butanone butyl (1-methylbutyl) hydrazone, 1, 1-dibutyl-2, 2-dimethylhydrazine, and 1, 1- ...