Palladium catalyzed arylation of malonate accompanying in situ dealkoxycarbonylation

…, K Inamoto, M Uchiyama, T Sakamoto

Index: Kondo; Inamoto; Uchiyama; Sakamoto Chemical Communications, 2001 , # 24 p. 2704 - 2705

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Citation Number: 13

Abstract

Introduction of an sp 3 carbon side chain into an aromatic ring is one of the important process in organic synthesis and many works have been done using palladium catalyzed reactions. 1 Various approaches have been studied for the synthesis of aryl acetates using coupling reactions 2–4 and very recently significant progress has been made for direct introduction of an acetic acid ester moiety into aromatic rings using palladium catalyzed reactions. 5 On the other ...