Synthesis and optical properties of coumarins and iminocoumarins: Estimation of ground-and excited-state dipole moments from a solvatochromic shift and theoretical …

…, D Kheffache, B Boutemeur-Kheddis, M Hamdi

Index: Rabahi, Amal; Makhloufi-Chebli, Malika; Hamdi, Safouane M.; Silva, Artur M.S.; Kheffache, Djaffar; Boutemeur-Kheddis, Baya; Hamdi, Maamar Journal of Molecular Liquids, 2014 , vol. 195, p. 240 - 247

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Citation Number: 6

Abstract

Abstract The optical properties of coumarin and iminocoumarin were investigated in different solvents by UV/vis absorption and fluorescence spectroscopy at room temperature (298 K). These compounds were characterized by UV–vis, FT-IR, mass spectroscopy and NMR. A bathochromic shift is observed in absorption and fluorescence spectra of our molecules with increasing solvent polarity. Solvatochromic correlations were used to obtain the ground- ...