Organogold (I) Phosphanes in Palladium??Catalyzed Cross??Coupling Reactions in Aqueous Media

M Peña??López, LA Sarandeses…

Index: Pena-Lopez, Miguel; Sarandeses, Luis A.; Perez Sestelo, Jose European Journal of Organic Chemistry, 2013 , # 13 p. 2545 - 2554

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Citation Number: 4

Abstract

Abstract Cross-coupling reaction of organogold (I) phosphanes with organic electrophiles in aqueous media has been investigated. Reactions between isolated aryl-, alkenyl-, or alkynylgold (I) phosphanes and aryl halides or triflates, alkenyl halides, and allyl acetates proceed under palladium catalysis conditions at room temperature or 80 C in water with THF as a co-solvent. The coupling reactions give good yields and are highly versatile and ...