ACS Catalysis

Au-NHC@ Porous organic polymers: Synthetic control and its catalytic application in alkyne hydration reactions

W Wang, A Zheng, P Zhao, C Xia, F Li

Index: Wang, Wenlong; Zheng, Anmin; Zhao, Peiqing; Xia, Chungu; Li, Fuwei ACS Catalysis, 2014 , vol. 4, # 1 p. 321 - 327

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Citation Number: 29

Abstract

The synthetic control and functions of porous organic polymers (POPs) with N-heterocyclic carbene gold (I)(Au-NHC@ POPs) are described in this article. A series of Au-NHC@ POPs with tunable physical properties such as surface area and pore size distribution were first synthesized via Sonogashira chemistry by differing monomer strut lengths and concentration during polymerization; a controllable transition from nonporous to microporous and the ...