M3X13 type of equilateral-triangular molybdenum metal atom cluster compound with several unprecedented features:[Mo3 (. mu. 3-CH3C)(. mu. 2-Br) 3 (. eta. 2,. mu. 2 …

A Birnbaum, FA Cotton, Z Dori, M Kapoh…

Index: Birnbaum, Amira; Cotton, F. Albert; Dori, Zvi; Kapon, Moshe; Marler, David; Reisner, George M. Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2405 - 2410

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Citation Number: 7

Abstract

Abstract: From the reaction of Mo (CO), with a refluxing mixture of acetic acid and acetic anhydride in the presence of NaBr and under nitrogen, the title compound is obtained after a suitable workup in which the reaction mixture is diluted with water and the trinuclear cation is adsorbed on a cation-exchange resin. The perchlorate salt was characterized by X-ray crystallography. It forms crystals in space group P2,/n with 2= 4 and the following unit cell ...