Enantioselective Total Synthesis and Absolute Configuration of Apiosporic Acid

M Gärtner, D Kossler, D Pflästerer…

Index: Jervis, Peter J.; Cox, Liam R. Journal of Organic Chemistry, 2008 , vol. 73, # 19 p. 7616 - 7624

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Citation Number: 3

Abstract

... The Journal of Organic ... J. Org. Chem. ... (3S)-3-[(Trityloxy)methyl]pent-4-en-1-ol (6) DIBAL-H (1 M in hexanes, 3.2 mL, 3.2 mmol) was added dropwise to a solution of 4 (497 mg, 1.29 mmol) in dry THF (10 mL) at −55 °C. Complete conversion was reached after 1 h [TLC: R f (4 ...