ChemPlusChem

Water??Soluble Ionic Palladium Complexes: Effect of Pendant Ionic Groups on Palladium Nanoparticles and Suzuki–Miyaura Reaction in Neat Water

L Li, T Wu, J Wang, R Wang

Index: Li, Liuyi; Wu, Tao; Wang, Jinyun; Wang, Ruihu ChemPlusChem, 2014 , vol. 79, # 2 p. 257 - 265

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Citation Number: 4

Abstract

Abstract Three ionic nitrogen-containing chelating ligands (L1–L3) are synthesized readily through alkylation and quaternization of 2, 2′-dipyridylamine. The charge distributions and natural bond orbital analyses of their cations are implemented by using density functional theory calculations. The catalytic performances of their water-soluble palladium complexes are evaluated preliminarily by using the Suzuki–Miyaura cross-coupling reaction, and ...