Tetrahedron letters

Rapid reductive-carboxylation of secondary amines. One pot synthesis of tertiary N-methylated amines

S Ram, RE Ehrenkaufer

Index: Ram, Siya; Ehrenkaufer, Richard E. Tetrahedron Letters, 1985 , vol. 26, # 44 p. 5367 - 5370

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Citation Number: 22

Abstract

Abstract Various tertiary N-methylated amines were synthesized by using a new reductive- carboxylation approach. Secondary amines, on carboxylation with carbon dioxide under moderate reaction conditions, afforded their corresponding carbamate esters, which, on Full-