Tetrahedron

Thiosulfonic s-esters-511For Part 3 and 4 in the same series, see Ref. 13 and 26.. Mechanistic aspects of the reaction with chlorotrimethylsilane and sodium iodide

R Caputo, C Ferreri, G Palumbo

Index: Palumbo, Giovanni; Parrilli, Michelangelo; Neri, Orsola; Ferreri, Carla; Caputo, Romualdo Tetrahedron Letters, 1982 , vol. 23, # 23 p. 2391 - 2394

Full Text: HTML

Citation Number: 8

Abstract

Thiosulfonic S-esters (1) are readily converted to disulfides (2) by chlorotrimethylsilane and sodium iodide. The reaction is shown to proceed through a complex mechanism, and more than one conversion pathway to disulfides must be considered. Evidence is presented for