Journal of Heterocyclic Chemistry

Differing reactivities and products in the reaction of some N??methylimidazol??2??yl, oxazol??2??yl??and thiazol??2??ylsilanes and??stannanes with acid chlorides

P Jutzi, U Gilge

Index: Jutzi, Peter; Gilge, Ullrich Journal of Heterocyclic Chemistry, 1983 , vol. 20, p. 1011 - 1014

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Citation Number: 14

Abstract

Abstract Some new N-methylimidazoles, oxazoles and thiazoles (compounds 7-15) with a keto-function in the 2-position have been synthesized by the reaction of heterocyclic substituted silanes and stannanes with the corresponding acid chlorides. In cases where the silylated heterocycles needed more drastic reaction conditions the use of the stannylated heterocycles was indicated. In the reaction of benzothiazol-2-yltrimethyl-stannane (6) with ...