Transition-state geometries and stereoselectivity of alkylidenecarbene addition to olefins. An experimental and theoretical investigation

Y Apeloig, M Karni, PJ Stang…

Index: Journal of the American Chemical Society, , vol. 105, # 14 p. 4781 - 4792

Full Text: HTML

Citation Number: 69

Abstract

... (1) For reviews and pertinent references see: Kirmse, W. 'Carbene Chemistry”, 2nd 4.; Academic Press: New York, 1971. ... The University of Utah. 0002-7863/83/1505-4781$01.50/0 0 1983 American Chemical Society Page 2. 4782 J. Am. Chem. ... Scheme I Vol. 105, No. 14, 1983 ...

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N/A Structure

99809-11-7

N/A

Isobutylene Structure

115-11-7

Isobutylene

~%

4-Methyl-2-pentyne Structure

21020-27-9

4-Methyl-2-pentyne

1-tert-butoxy-2,3-dimethyl-but-1-ene Structure

85851-34-9

1-tert-butoxy-2...

Detail
N/A Structure

99809-11-7

N/A

Isobutylene Structure

115-11-7

Isobutylene

~%

4-Methyl-2-pentyne Structure

21020-27-9

4-Methyl-2-pentyne

1-tert-butoxy-2,3-dimethyl-but-1-ene Structure

85851-35-0

1-tert-butoxy-2...

Detail
3,3-Dimethyl-1-butene Structure

558-37-2

3,3-Dimethyl-1-...

N/A Structure

99809-11-7

N/A

~%

4,4-dimethylpent-2-yne Structure

999-78-0

4,4-dimethylpen...

1-tert-butoxy-2,3-dimethyl-but-1-ene Structure

85851-34-9

1-tert-butoxy-2...

Detail
3,3-Dimethyl-1-butene Structure

558-37-2

3,3-Dimethyl-1-...

N/A Structure

99809-11-7

N/A

~%

4,4-dimethylpent-2-yne Structure

999-78-0

4,4-dimethylpen...

1-tert-butoxy-2,3-dimethyl-but-1-ene Structure

85851-35-0

1-tert-butoxy-2...

Detail
3,3-Dimethyl-1-butene Structure

558-37-2

3,3-Dimethyl-1-...

N/A Structure

99809-12-8

N/A

~%

4,4-dimethylpent-2-yne Structure

999-78-0

4,4-dimethylpen...

(E)-1-tert-butoxy-2,3,3-trimethyl-1-butene Structure

85851-38-3

(E)-1-tert-buto...

Detail
N/A Structure

99809-12-8

N/A

Isobutylene Structure

115-11-7

Isobutylene

~%

4,4-dimethylpent-2-yne Structure

999-78-0

4,4-dimethylpen...

(E)-1-tert-butoxy-2,3,3-trimethyl-1-butene Structure

85851-38-3

(E)-1-tert-buto...

Detail
3,3-Dimethyl-1-butene Structure

558-37-2

3,3-Dimethyl-1-...

2-methylbut-1-en-1-yl trifluoromethanesulfonate Structure

57155-03-0

2-methylbut-1-e...

~%

Pent-2-yne Structure

627-21-4

Pent-2-yne

N/A Structure

53282-42-1

N/A

Detail
3,3-Dimethyl-1-butene Structure

558-37-2

3,3-Dimethyl-1-...

2-methylbut-1-en-1-yl trifluoromethanesulfonate Structure

57155-03-0

2-methylbut-1-e...

~%

Pent-2-yne Structure

627-21-4

Pent-2-yne

N/A Structure

53282-41-0

N/A

Detail
2-methylbut-1-en-1-yl trifluoromethanesulfonate Structure

57155-03-0

2-methylbut-1-e...

Isobutylene Structure

115-11-7

Isobutylene

~%

Pent-2-yne Structure

627-21-4

Pent-2-yne

N/A Structure

53282-42-1

N/A

Detail
2-methylbut-1-en-1-yl trifluoromethanesulfonate Structure

57155-03-0

2-methylbut-1-e...

Isobutylene Structure

115-11-7

Isobutylene

~%

Pent-2-yne Structure

627-21-4

Pent-2-yne

N/A Structure

53282-41-0

N/A

Detail

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