Tetrahedron Letters

Cp2TiCl2-catalyzed grignard reactions. 2. Reactions with ketones and aldehydes

F Sato, T Jinbo, M Sato

Index: Sato, Fumie; Jinbo, Takamasa; Sato, Masao Tetrahedron Letters, 1980 , vol. 21, p. 2171 - 2174

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Citation Number: 44

Abstract

The reaction of Grignard reagents with ketones or aldehydes in the presence of a catalytic amount of Cp 2 TiCl 2 leads to the corresponding reduction products in high yields. Cp 2 TiH intermediate was proposed to account for this observation. ... Tetrahedron Letters Vol. 21, pp 2171 - 2174 00-4039/80/0522-2171,02.00/0 Pergamon Press Ltd. 1980. Printed in Great Britain Cp2T'C12-CATALYZED GRIGNARD REACTIONS. 2. REACTIONS WITH KETONES AND ...