Orthogonal Photocleavage of a Monochromophoric Linker

L Kammari, T Šolomek, BP Ngoy…

Index: Kammari, Laxminarayana; Solomek, Tomas; Ngoy, Bokolombe Pitchou; Heger, Dominik; Klan, Petr Journal of the American Chemical Society, 2010 , vol. 132, # 33 p. 11431 - 11433

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Citation Number: 18

Abstract

The aim of this work was to design a photocleavable monochromophoric linker connecting two molecules (or a support) through different functionalities, which can be disconnected selectively and orthogonally upon irradiation. Such an approach differs from that utilized with linkers that can be removed using a combination of photochemical and dark processes(1, 2, 8) or employing a bichromophoric system.(7, 9) Here we report on a linker that combines the properties of ...

~76%

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