Synthesis of Products Related to Vitamin A. IV. The Application of the Darzens Reaction to β-Ionone1a

NA Milas, SW Lee, E Sakal, HC Wohlers…

Index: Milas et al. Journal of the American Chemical Society, 1948 , vol. 70, p. 1584,1589

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Citation Number: 11

Abstract

Summary The use of electromotive-force measurements of hydrogen-silver chloride cells without liquid junction in resolving the constants for the overlapping dissociation steps of weak dibasic and tri-basic acids is discussed. When one constant of an constants* overlapping pair is known, the second can be derived from studies of solutions of the appropriate primary or secondary acid salt with added alkali chloride. The equations for ...