J. Chem. Soc., Faraday Trans.

Pivalic acid as combined buffer and scavenger for studies of cloud water chemistry with pulse radiolysis

T Nauser, RE Bühler

Index: Nauser, Thomas; Buehler, Rolf E. Journal of the Chemical Society, Faraday Transactions, 1994 , vol. 90, # 24 p. 3651 - 3656

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Citation Number: 9

Abstract

The reactions of cloud water with transition-metal ions may be studies using pivalic acid as buffer and˙ OH scavenger. Commonly used phosphate buffers form strong complexes that may have an important effect on reaction kinetics. Low solubility products limit transition- metal ion concentrations to very low levels (m