Liebigs Annalen der Chemie

Synthesis of sphingosine relatives, IX. Synthesis of (2S, 3R, 4E)??1??O??(β??D??glucopyranosyl)??N??[24??(linoleoyloxy) tetracosanoyl]??4??sphingenine. The structure …

K Mori, H Nishio

Index: Mori, Kenji; Nishio, Hiroyuki Liebigs Annalen der Chemie, 1991 , # 3 p. 253 - 257

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Citation Number: 3

Abstract

Abstract (2S, 3R, 4E)-1-O-(β-D-Glucopyranosyl)-N-[24-(linoleoyloxy) tetracosanoyl)-4- sphingenine (1) was synthesized from D-glucose (A),(2S, 3R, 4E)-4-sphingenine (sphingosine, B), 24-hydroxytetracosanoic acid (C) and linoleic acid (D). The 1 H-NMR spectrum of synthetic 1 was different from that of the esterified cerebroside which was isolated as a tissue-characteristic compound in the epidermis of footpad and dorsal skin of ...