The Journal of Organic Chemistry

Phase transfer catalyzed hydrolysis of thioacetals using pyridinium hydrobromide perbromide

GS Bates, J O'Doherty

Index: Bates, Gordon S.; O'Doherty, James Journal of Organic Chemistry, 1981 , vol. 46, # 8 p. 1745 - 1747

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Citation Number: 16

Abstract

'ZH5 74c 3b 11 CH3 CH= CHCOzCH3 CZH, 83 10 13 nC, H, CHO'ZH5 80 2, 10 a Complexes 1 and 2 may be used interchangeably.* Yields are of purified isolated material. Reaction carried out in aqueous acetonitrile (no pyridine), the corresponding a-dicarbonyl compounds. In addition, such a method might also be a useful complement to the existing methods of thioketal hydrolysi~.~ We have found that a wide range of thioacetals and ...