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e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Unusual pathway of the tantalum-catalyzed carboalumination reaction of alkenes with triethylaluminum

RM Sultanov, EV Samoilova, AR Tulyabaev…

Index: Tetrahedron Letters, , vol. 54, # 48 p. 6619 - 6623

Full Text: HTML

Citation Number: 2

Abstract

... Tetrahedron Letters. Volume 54, Issue 48, 27 November 2013, Pages 6619–6623. Cover image Cover image. ... 4. In this Letter, we report the first use of TaCl 5 as a catalyst for the carboalumination of linear alkenes and norbornenes with Et 3 Al. ...

 Related Synthetic Route
octene Structure

111-66-0

octene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

1-Octanol Structure

111-87-5

1-Octanol

3-methylnonan-1-ol Structure

22663-64-5

3-methylnonan-1-ol

Detail
1-decene Structure

872-05-9

1-decene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

2-methylmercapto-3-formylthiophene diethylacetal Structure

71526-27-7

2-methylmercapt...

Decan-1-ol Structure

112-30-1

Decan-1-ol

Detail
octene Structure

111-66-0

octene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

Octane Structure

111-65-9

Octane

3-Methylnonane Structure

5911-04-6

3-Methylnonane

1-decene Structure

872-05-9

1-decene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

Decane Structure

124-18-5

Decane

3-Methylundecane Structure

1002-43-3

3-Methylundecane

1-hexene Structure

592-41-6

1-hexene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

2-Ethylhexanol Structure

104-76-7

2-Ethylhexanol

3-METHYL-1-HEPTANOL Structure

1070-32-2

3-METHYL-1-HEPTANOL

Detail
1-hexene Structure

592-41-6

1-hexene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

2-Ethylhexanol Structure

104-76-7

2-Ethylhexanol

3-METHYL-1-HEPTANOL Structure

1070-32-2

3-METHYL-1-HEPTANOL

Detail
1-hexene Structure

592-41-6

1-hexene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

2-Ethylhexanol Structure

104-76-7

2-Ethylhexanol

3-METHYL-1-HEPTANOL Structure

1070-32-2

3-METHYL-1-HEPTANOL

Detail
1-decene Structure

872-05-9

1-decene

Triethylaluminum Structure

97-93-8

Triethylaluminum

~%

Decane Structure

124-18-5

Decane

3-Methylundecane Structure

1002-43-3

3-Methylundecane

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Detail Synthetic Route


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