New pentahydroxypentylpyrazoles from the reactions of d-mannose and d-galactose methylhydrazones with nitroalkenes

M Gómez-Guillén, F Hans-Hans, JML Simon…

Index: Gomez-Guillen, Manuel; Hans-Hans, Felisa; Simon, Jose Maria Lassaletta; Martin-Zamora, Maria Eloisa Carbohydrate Research, 1989 , vol. 189, p. 349 - 358

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Citation Number: 13

Abstract

“In MeOH. bin EtOH. Shoulder. of the reactions leading to the (pentitol-1-yl) pyrazoles 7-12 is again shown by the 6 value (6.18-6.94) for the resonance of the pyrazole proton in 7, 10, 11, and their derivatives, which accords with the data reported5 for H-4 in other l- methylpyrazoles but not with those corresponding to H-5. The J values for alkyl protons of the polyol side-chain in compounds having the D-manno configuration (7-9, and 13-15) ...