Tetrahedron letters

The nef reaction on trialkylsilyl nitronates promoted by m-chloroper-benzoic acid. An efficient route to α-alkoxyketones from nitroalkanes.

JM Aizpurua, M Oiarbide, C Palomo

Index: Aizpurus, J. M.; Oiarbide, M.; Palomo, C. Tetrahedron Letters, 1987 , vol. 28, # 44 p. 5361 - 5364

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Citation Number: 32

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Treatment of a nitroalkene with nucleophiles, followed by silylation of the resulting nitroalkane and subsequent treatment with m-chloroperbenzoic acid, provides α-functionalized carbonyl compounds in good yields. ... Treatment of a nitroalkene with nucleophiles followed by ...