Gaseous Nitrogen Dioxide for Sustainable Oxidative Deprotection of Trimethylsilyl Ethers

M Javaheri, MR Naimi-Jamal…

Index: Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 187, # 1 p. 142 - 148

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Abstract

... View all related articles. ... Phosphorus Sulfur Silicon Relat. ... When the NO 2 radical binds to the silicon atom of the TMS ether 1, it leaves the immediately trapped oxygen radical 2, giving the HNO 3 ester 3 (3f was detected by MS and FTIR spectra, upon evaporation in early stages ...