Synlett

Room-Temperature Palladium-Catalyzed Allyl Cross-Coupling Reaction with Boronic Acids Using Phosphine-Free Hydrazone Ligands

T Mino, K Kajiwara, Y Shirae, M Sakamoto, T Fujita

Index: Mino, Takashi; Kajiwara, Kenji; Shirae, Yoshiaki; Sakamoto, Masami; Fujita, Tsutomu Synlett, 2008 , # 17 p. 2711 - 2715

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Citation Number: 2

Abstract

Palladium-catalyzed allyl cross-coupling reaction of allylic acetates with a variety of boronic acids at room temperature using a catalytic amount of Pd(OAc) 2 with phosphine-free hydrazone as a ligand gave the allylbenzene derivatives in good yields. ... Palladium-catalyzed CC bond formation reactions have been recognized as powerful tools in multiple organic transformations. [¹] Palladium-catalyzed cross-coupling of aryl and vinyl halides with aryl- and vinylboronic ...