Tetrahedron

Smectic A liquid crystals from dihydrazide derivatives with lateral intermolecular hydrogen bonding

D Pang, H Wang, M Li

Index: Pang, Dongmei; Wang, Haitao; Li, Min Tetrahedron, 2005 , vol. 61, # 25 p. 6108 - 6114

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Citation Number: 44

Abstract

Six dissymmetrical dihydrazide derivatives, N-(4-alkoxybenzoyl)-N′-(4′-nitrobenzoyl) hydrazine (Cn–NO2) and N-(4-alkoxybenzoyl)-N′-(4′-biphenyl carbonyl) hydrazine (Cn– Ph), were synthesized and investigated by means of differential scanning calorimetry, polarized optical microscopy and wide angle X-ray diffraction. The compounds exhibit smectic A1 phase. Based on the results of 1H NMR and variable temperature FT-IR ...