Interaction of perfluoropent-2-ene and its 2-amino-4-imino derivative with ethylenediamine and with diethylenetriamine

…, YV Burgart, ON Chupakhin, M Font-Altaba…

Index: Saloutin, V. I.; Skryabina, Z. E.; Burgart, Y. V.; Chupakhin, O. N.; Font-Altaba, M.; et al. Journal of Fluorine Chemistry, 1994 , vol. 69, # 1 p. 25 - 30

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Citation Number: 20

Abstract

Abstract 5, 7-Trifluoromethyl-6-fluoro-2, 3-dihydro-1H-1, 4-diazepine has been prepared by the reaction of perfluoropent-2-ene (or 2-amino-4-iminoperfluoropent-2-ene) with ethylenediamine. Both perfluoropent-2-ene and 2-amino-4-iminoperfluoropent-2-ene were found to react with diethylenetriamine to form 1, 9-trifluoromethyl-3, 4, 6, 7-tetrahydro-2H- pyrazino [1, 2a] pyrazine (established by X-ray study). Some salts and the complex with ...