The Journal of organic chemistry

Multidirectional Cobalt-Catalyzed Diels–Alder/1, 4-Hydrovinylation Sequences

F Erver, JR Kuttner, G Hilt

Index: Erver, Florian; Kuttner, Julian R.; Hilt, Gerhard Journal of Organic Chemistry, 2012 , vol. 77, # 19 p. 8375 - 8385

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Citation Number: 10

Abstract

The combination of two powerful cobalt-catalyzed carbon–carbon bond forming transformations, namely, the Diels–Alder and the 1, 4-hydrovinylation reaction, in a tandem or a sequential one-pot procedure, opened up a concise and efficient route to polysubstituted aromatic systems and cyclohex-3-enone derivatives. Furthermore, ozonolysis of the latter products led to polycarbonyl compounds with tailored carbonyl ...