Vanadium (II) porphyrin complexes: synthesis and characterization. Crystal structure of 2, 3, 7, 8, 12, 13, 17, 18-octaethylporphinatobis-(dimethylphenylphosphine) …

…, JM Barbe, R Guilard, H Oumous, C Lecomte…

Index: Poncet, Jean-Luc; Barbe, Jean-Michel; Guilard, Roger; Oumous, Hassan; Lecomte, Claude; Protas, Jean Journal of the Chemical Society, Chemical Communications, 1982 , # 24 p. 1421 - 1422

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Citation Number: 6

Abstract

The vanadium (II) porphyrins VII (PPhMe2) 2 (porp) containing phosphine ligands have been prepared from VII (X2)(porp)[porp= octaethylporphinato (oep), meso- tetraphenylporphinato, meso-tetra-m-tolylporphinato, meso-tetra-p-tolylporphinato] and the crystal structure of VII (PPhMe2) 2 (oep) has been solved by X-ray diffraction methods; the first observations of interactions between vanadium (II) porphyrins and molecular oxygen ...