Orthoamide, XXXII. Umsetzungen von tert??Butoxy??N, N, N′, N′??tetramethylmethandiamin mit NH??und CH??aciden Verbindungen

W Kantlehner, F Wagner…

Index: Kantlehner, Willi; Wagner, Fritz; Bredereck, Hellmut Liebigs Annalen der Chemie, 1980 , # 3 p. 344 - 357

Full Text: HTML

Citation Number: 14

Abstract

Abstract tert-Butoxy-N, N, N′, N′-tetramethylmethandiamin (1) reagiert mit N-Formylglycin- ethylester (2) und mit N-Formyl-β-alanin-ethylester (9) zu den Aminomethylenverbindungen 3 bzw. 10. Glycinethylester wird sowohl durch 1 als auch durch Dimethylaminoformaldehyd- dimethylacetal (5) an der NH 2-Gruppe zu 6 aminomethyleniert. Ebenso wie 3 setzt sich auch 6 mit 1 zum Amidin 4 um. N-Monosubstituierte Formamide werden durch 1 in ...

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tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

3-Dimethylamino-2-(formylaminomethyl)acrylsaeure-ethylester Structure

74119-34-9

3-Dimethylamino...

~0%

Ethyl 3-(dimethylamino)acrylate Structure

924-99-2

Ethyl 3-(dimeth...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Ethyl glycinate Structure

459-73-4

Ethyl glycinate

~0%

ethyl N-((dimethylamino)methylene)glycinate Structure

30766-78-0

ethyl N-((dimet...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-FORMYL-BETA-ALANINE ETHYL ESTER Structure

34433-91-5

N-FORMYL-BETA-A...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

Ethyl 3-(dimethylamino)acrylate Structure

924-99-2

Ethyl 3-(dimeth...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-FORMYL-BETA-ALANINE ETHYL ESTER Structure

34433-91-5

N-FORMYL-BETA-A...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

3-Dimethylamino-2-(formylaminomethyl)acrylsaeure-ethylester Structure

74119-34-9

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N,N-Dimethylformamide dimethyl acetal Structure

4637-24-5

N,N-Dimethylfor...

Ethyl glycinate Structure

459-73-4

Ethyl glycinate

~0%

ethyl N-((dimethylamino)methylene)glycinate Structure

30766-78-0

ethyl N-((dimet...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Ethyl glycinate Structure

459-73-4

Ethyl glycinate

~0%

3-Dimethylamino-2-(dimethylaminomethylenamino)acrylsaeure-ethylester Structure

74119-32-7

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-Formylglycine ethyl ester Structure

3154-51-6

N-Formylglycine...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

3-Dimethylamino-2-(dimethylaminomethylenamino)acrylsaeure-ethylester Structure

74119-32-7

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

3-Dimethylamino-2-(formylamino)acrylsaeure-ethylester Structure

74119-33-8

3-Dimethylamino...

~0%

3-Dimethylamino-2-(dimethylaminomethylenamino)acrylsaeure-ethylester Structure

74119-32-7

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Ethyl isocyanoacetate Structure

2999-46-4

Ethyl isocyanoa...

~0%

3-Dimethylamino-2-isocyanacrylsaeure-ethylester Structure

87951-12-0

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-Formylglycine ethyl ester Structure

3154-51-6

N-Formylglycine...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

3-Dimethylamino-2-(formylamino)acrylsaeure-ethylester Structure

74119-33-8

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Formamide,N-(phenylmethyl) Structure

6343-54-0

Formamide,N-(ph...

~57%

N'-benzyl-N,N-dimethylmethanimidamide Structure

27159-75-7

N'-benzyl-N,N-d...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

N/A Structure

88333-03-3

N/A

~0%

N2-(2-Dimethylamino-1-phenylvinyl)-N1,N1-dimethylformamidin Structure

74119-37-2

N2-(2-Dimethyla...

tert-Butanol Structure

75-65-0

tert-Butanol

Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

3-Dimethylamino-2-(formylaminomethyl)acrylsaeure-ethylester Structure

74119-34-9

3-Dimethylamino...

~0%

Ethyl 3-(dimethylamino)acrylate Structure

924-99-2

Ethyl 3-(dimeth...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Ethyl glycinate Structure

459-73-4

Ethyl glycinate

~0%

ethyl N-((dimethylamino)methylene)glycinate Structure

30766-78-0

ethyl N-((dimet...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-methylformamide Structure

123-39-7

N-methylformamide

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

N1,N1,N2-Trimethylformamidine Structure

1609-01-4

N1,N1,N2-Trimet...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
N-FORMYL-BETA-ALANINE ETHYL ESTER Structure

34433-91-5

N-FORMYL-BETA-A...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

Ethyl 3-(dimethylamino)acrylate Structure

924-99-2

Ethyl 3-(dimeth...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-FORMYL-BETA-ALANINE ETHYL ESTER Structure

34433-91-5

N-FORMYL-BETA-A...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

3-Dimethylamino-2-(formylaminomethyl)acrylsaeure-ethylester Structure

74119-34-9

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-Ethylformamide Structure

627-45-2

N-Ethylformamide

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

N'-ethyl-N,N-dimethylmethanimidamide Structure

74119-36-1

N'-ethyl-N,N-di...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
N,N-Dimethylformamide dimethyl acetal Structure

4637-24-5

N,N-Dimethylfor...

Ethyl glycinate Structure

459-73-4

Ethyl glycinate

~0%

ethyl N-((dimethylamino)methylene)glycinate Structure

30766-78-0

ethyl N-((dimet...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Ethyl glycinate Structure

459-73-4

Ethyl glycinate

~0%

3-Dimethylamino-2-(dimethylaminomethylenamino)acrylsaeure-ethylester Structure

74119-32-7

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Formamide, N-phenyl Structure

103-70-8

Formamide, N-phenyl

~0%

Methanimidamide,N,N-dimethyl-N'-phenyl Structure

1783-25-1

Methanimidamide...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

3-Dimethylamino-2-(formylamino)acrylsaeure-ethylester Structure

74119-33-8

3-Dimethylamino...

~0%

3-Dimethylamino-2-(dimethylaminomethylenamino)acrylsaeure-ethylester Structure

74119-32-7

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Formamide, N-phenyl Structure

103-70-8

Formamide, N-phenyl

~55%

Methanimidamide,N,N-dimethyl-N'-phenyl Structure

1783-25-1

Methanimidamide...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
N-N-Propylformamide Structure

6281-94-3

N-N-Propylformamide

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

N2-n-propyl-N1,N1-dimethylformamidine Structure

32150-25-7

N2-n-propyl-N1,...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Formamide,N-(phenylmethyl) Structure

6343-54-0

Formamide,N-(ph...

~0%

N'-benzyl-N,N-dimethylmethanimidamide Structure

27159-75-7

N'-benzyl-N,N-d...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
N-Formylglycine ethyl ester Structure

3154-51-6

N-Formylglycine...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

3-Dimethylamino-2-(dimethylaminomethylenamino)acrylsaeure-ethylester Structure

74119-32-7

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Ethyl isocyanoacetate Structure

2999-46-4

Ethyl isocyanoa...

~0%

3-Dimethylamino-2-isocyanacrylsaeure-ethylester Structure

87951-12-0

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-Formylglycine ethyl ester Structure

3154-51-6

N-Formylglycine...

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

3-Dimethylamino-2-(formylamino)acrylsaeure-ethylester Structure

74119-33-8

3-Dimethylamino...

Dimethylamine Structure

124-40-3

Dimethylamine

Detail Learn More
N-methylformamide Structure

123-39-7

N-methylformamide

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

N1,N1,N2-Trimethylformamidine Structure

1609-01-4

N1,N1,N2-Trimet...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
N-N-Propylformamide Structure

6281-94-3

N-N-Propylformamide

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

N2-n-propyl-N1,N1-dimethylformamidine Structure

32150-25-7

N2-n-propyl-N1,...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
N-Ethylformamide Structure

627-45-2

N-Ethylformamide

tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

~0%

N'-ethyl-N,N-dimethylmethanimidamide Structure

74119-36-1

N'-ethyl-N,N-di...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Formamide,N-(phenylmethyl) Structure

6343-54-0

Formamide,N-(ph...

~0%

N'-benzyl-N,N-dimethylmethanimidamide Structure

27159-75-7

N'-benzyl-N,N-d...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More
tert-Butoxy bis(dimethylamino)methane Structure

5815-08-7

tert-Butoxy bis...

Formamide, N-phenyl Structure

103-70-8

Formamide, N-phenyl

~0%

Methanimidamide,N,N-dimethyl-N'-phenyl Structure

1783-25-1

Methanimidamide...

N,N-Dimethylformamide Structure

68-12-2

N,N-Dimethylfor...

Detail Learn More

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