Influence of titania surface on 1, 2-chlorine shift in. beta.-chlorine-substituted radicals as studied by radiation chemistry and photocatalysis

Y Mao, C Schoeneich, KD Asmus

Index: Mao, Yun; Schoeneich, Christian; Asmus, Klaus-Dieter Journal of Physical Chemistry, 1992 , vol. 96, # 21 p. 8522 - 8529

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Citation Number: 9

Abstract

The influence of surfacespecific parameters on the photocatalytically induced oxidative degradation of halogenated hydrocarbons in aqueous Ti02 suspensions has been evaluated by comparing the results obtained in this heterogeneous system with those from y- irradiated homogeneous aqueous solutions. A 1, Zchlorine shift known to occur in &chlorinated alkyl radicals and the products obtained upon degradation of these radicals ( ...

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