Solvent-induced selectivity switching: intermolecular allylsilylation, arylsilylation, and silylation of alkynes over montmorillonite catalyst

K Motokura, S Matsunaga, A Miyaji, T Yashima…

Index: Tetrahedron Letters, , vol. 52, # 50 p. 6687 - 6692

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Citation Number: 11

Abstract

... Tetrahedron Letters. Volume 52, Issue 50, 14 December 2011, Pages 6687–6692. ... on allylsilylations, we found that arylsilylation and silylation proceeded selectively in the presence of solvents having relatively high nucleophilicity (Scheme 2B and C). In this Letter, we describe ( ...