The Journal of Organic Chemistry

Nitrile oxides. XII. Cycloaliphatic and aliphatic stable nitrile oxides

C Grundmann, SK Datta

Index: Grundmann,C.; Datta,S.K. Journal of Organic Chemistry, 1969 , vol. 34, # 6 p. 2016 - 2018

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Citation Number: 35

Abstract

Simple aliphatic nitrile oxides are extremely unstable and isomerize even at 0'in dilute solutions within seconds or, at best, minutes to the corresponding dialkylfurazan oxides (furoxans, 1, 2, &oxadiazole 1-oxides). 2J Only recently a few representatives of aliphatic nitrile oxides have been obtained &s monomew by working at temperatures of approximately-4OO.'Trimethylacetonitrile oxide [1,(C&) aC-ChN+ O] is the only member of ...