Nickel and palladium catalysed reaction of triethyl phosphite with aryl halides under microwave irradiation

…, PA Jaffres, G Maheut, M Mosaddak…

Index: Villemin, Didier; Elbilali, Abdelghani; Simeon, Fabrice; Jaffres, Paul-Alain; Maheut, Geraldine; Mosaddak, Mahjouba; Hakiki, Abdelhack Journal of Chemical Research - Part S, 2003 , # 7 p. 436 - 437

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Citation Number: 15

Abstract

The reaction of triethyl phosphite with aryl halides catalysed by nickel (0) complexes has been described previously by Tavs.1 This reaction is one of the more convenient synthesis of aryl phosphonates2 although it involves rather extreme conditions (200C, 6h). Microwave dielectric heating effects are increasingly used in organic synthesis.3 Microwave irradiation and the use of a resonance cavity was recently employed to activate catalysis by transition metal complexes in ...