Chiral Benzylic Carbocations: Low-Temperature NMR Studies and Theoretical Calculations

D Stadler, A Goeppert, G Rasul, GA Olah…

Index: Smonou, Ioulia; Orfanopoulos, Michael Synthetic Communications, 1990 , vol. 20, # 9 p. 1387 - 1397

Full Text: HTML

Citation Number: 35

Abstract

... Volume: Page: ... in reactions of less reactive electrophiles (carbonyl compounds,(6) imines,(7) oxonium ions,(8) iminium ions(9)) has been ... is in line with the fact that substitution reactions at alcohols 5 and 6 occurred with only modest diastereoselectivity.(12b, 20). ...