N, N-Dibromobenzenesulfonamide as a reagent for oxidative cleavage of oximes to their parent carbonyl compounds under non-aqueous and aprotic conditions

…, A Khazaei, M Shabani-Mahalli…

Index: Tajbakhsh, Mahmood; Khazaei, Ardeshir; Shabani-Mahalli, Majid; Ghorbani-Vaghei, Ramin Journal of Chemical Research, 2004 , # 2 p. 141 - 142

Full Text: HTML

Citation Number: 6

Abstract

Oximes are highly crystalline compounds extensively used for the purification and characterisation of carbonyl compounds. These compounds can also be used for the preparation of amides via the Beckman rearrangement.1 Since oximes can be prepared from non-carbonyl compounds,2 the regeneration of carbonyl compounds from oximes provides an alternative method for preparation of aldehydes and ketones. The classical recovery of ketones and ...