Observations on the reductive deoxygenation of aryl and α, β-unsaturated carbonyl compounds with chlorotrimethylsilane and zinc

…, MCS de Carrasco, CSV Frydrych-Houge…

Index: Banerjee, Ajoy K.; Carrasco, Maria C. Sulbaran de; Frydrych-Houge, Catherine S. V.; Motherwell, William B. Journal of the Chemical Society, Chemical Communications, 1986 , # 24 p. 1803 - 1805

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Abstract

Some time ago, we reported a novel general method for the direct deoxygenation of a carbonyl compound to give an alkene involving reaction with chlorotrimethylsilane and zinc.' The essential mechanistic features of the reaction, which has subsequently been utilised by several groups,2 are outlined in Scheme 1, and bear a direct resemblance to those ... Published on 01 January 1986. Downloaded by google on 19/02/2016 03:22:38.