Synthesis of Aliphatic Sulfur Pentafluorides by Oxidation of SF5-Containing Anisole, Phenols, and Anilines

…, T Pastyrikova, B Klepetarova, P Beier

Index: Pastyrikova, Tereza; Iakobson, George; Vida, Norbert; Pohl, Radek; Beier, Petr European Journal of Organic Chemistry, 2012 ,  # 11  p. 2123 - 2126

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Citation Number: 6

Abstract

4-(Pentafluorosulfanyl) catechol, 2-amino-4-(pentafluorosulfanyl) phenol, and 2-amino-5- (pentafluorosulfanyl) phenol undergo oxidation by lead tetraacetate at ambient temperature leading to dearomatization and the formation of SF5-substituted nitriles and esters of cis, cis- hexa-2, 4-dienedioic (muconic) acid in good yields. 4-(Pentafluorosulfanyl) phenol and 4- (pentafluorosulfanyl) anisole are oxidized by 30% aqueous hydrogen peroxide in ...