Determination of the inductive constant of the succinimide group from the reaction series of thermolysis of nitro esters

TK Goncharov, VV Dubikhin, GM Nazin…

Index: Goncharov; Dubikhin; Nazin; Fedorov; Shastin Russian Journal of General Chemistry, 2005 , vol. 75, # 6 p. 901 - 904

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Abstract

Abstract The inductive constant σ* of the succinimide group was determined using the previously obtained equation correlating the rate constant kl ofliquid-phase homolysis of the O-NO 2 bond in nitro esters with the σ* constants of electronegative substituents. The kinetics of thermolysis of N-nitroxymethyl-and N-(2-nitroxyethyl) succinimide in the melt and solutions was studied manometrically. Adequate data for kl were obtained. The σ* ...