A New Method for the Synthesis of Stannyl Ethers by Acid-Catalyzed Reaction of Alcohols with Allyltributylstannane.

S Yamago, T Yamada, R Nishimura, H Ito, Y Mino…

Index: Yamago, Shigeru; Yamada, Takeshi; Nishimura, Ryuji; Ito, Hiroki; Mino, Yosuke; Yoshida, Jun-Ichi Chemistry Letters, 2002 , # 2 p. 152 - 153

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Citation Number: 9

Abstract

Stannyl ethers are prepared by triflic acid-catalyzed reaction of alcohols with tributylstannane or allyltributylstannane at room temperature. The stannyl ethers thus prepared can be successfully used for the β-bromogycoside-mediated glycosylation reactions.